Synthesis, crystal structure and Hirshfeld surface analysis of a polymeric bismuthate(III) halide complex, (C6H6N3)2[BiCl5]·2H2O
نویسندگان
چکیده
The synthesis and the crystal structure of a new halide-bridged polymer, namely catena-poly[bis-(1,2,3-benzotriazolium) [[tetra-chlorido-bis-muth(III)]-μ-chlorido] dihydrate], {(C6H6N3)2[BiCl5]·2H2O} n are reported. The structure comprises polyanionic zigzag chains of formula [(BiCl5)2-] n running along the c-axis direction. The 1,2,3-benzotriazolium cations are linked between these polymer chains, via the water mol-ecules, giving rise to left- and right-handed helical chains. Hirshfeld surface analysis and fingerprint plots were used to decode the inter-molecular inter-actions in the crystal network and determine the contribution of the component units for the construction of the three-dimensional architecture.
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